كتاب دانلود مقاله : Effect of carbon content and calcination temperature on the electrochemical per
دانلود مقاله :
Effect of carbon content and calcination temperature on the electrochemical performance of lithium iron phosphate/carbon composites as cathode materials for lithium-ion batteries 2013
نويسندگان :
Xiaodong Wang , Ke Cheng,Jingwei Zhang,Laigui Yu,Jianjun Yang
فرمت: pdf
چكيده :
Lithium iron phosphate/carbon (LiFePO4/C) composites were prepared by aconvenient method with
water-soluble phenol-formaldehyde resin as the carbon precursor.The morphology,crystalline structure,
thermal stability, and composition of as-prepared LiFePO 4/C composites were investigated by scannin g
electron microscopy, X-ray diffraction,thermogravimetric analysis,and Raman spectrometry.Their elec-
trochemical performance was examined based on cyclic voltammogram with aLAND battery testing sys-
tem while the effect of carbon content and calcination temperature was highlighted.Results show that
carbon content and calcination temperature dramatical ly influencethe discharge capacities and rate per-
formance of LiFePO 4/C comp osites.The optimal calcination temperature is 700 C, and the optimal carbon
content (mass fraction)is 8.7%.The LiFePO 4/C composite prepared under the optimal conditions exhibits
an initial room temperat ure discharge capacity of 150.2 mA hg1 at a 0.2 Crate and aconstant discharge
capacity of about 105.7 mA hg1 at a 20.0 Crate after 50 cycles,showing promising potential as anovel
cathode material for lithium ion batteries.
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